2024, Volume 70(74), Issue 4 (December)

Contents

pages 1- 8   Download

Modern Mechano-Chemical Procedure for Obtaining a High-Strength Geopolymer Composite

LUCIAN PĂUNESCU, Daily Sourcing & Research SRL, Bucharest, Romania, lucianpaunescu16@gmail.com
ENIKÖ VOLCEANOV, Faculty of Engineering in Foreign Language, National University of Science and Technology “Politehnica” Bucharest, Romania; Metallurgical Research Institute SA Bucharest, Romania
BOGDAN VALENTIN PĂUNESCU, Consitrans SA Bucharest, Romania

pages 9 - 19   Download
DOI: 10.5281/zenodo.14581968
Abstract
Replacing the usual alkaline solution with sodium metasilicate nonahydrate as an alkaline activator of alumina-silicate waste for the manufacture of geopolymers represents a recent technical solution for significantly increasing their mechanical resistance. The principle of this method was tested in an own version by the authors’ team of the current work. Coal fly ash, river sand, and silica fume (nano-silica) were solid precursors used in the starting material mixture. Under the conditions of pressing the geopolymer powder (made by the conventional method) at the axial pressure of 400 daN·cm-2, compared to its value of 1000 daN·cm-2 used by (Nishikawa et al., 2022), the level of resistance to compression and flexure reached values very high, superior compared to that of usual geopolymers.
Keywords: geopolymer composite, alumina-silicate, sodium metasilicate nonahydrate, pressure, mechanical resistance

Effect of Inorganic Salts on the Solubilization of Phosphorus from Chemical Fertilizers

BIANCA-MARIA HĂISAN, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania
LOREDANA MUNTEANU, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania
DUMITRU BULGARIU, “Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Iaşi, Romania; Romanian Academy, Filial of Iaşi, Branch of Geography, Iaşi, Romania
RAMONA-ELENA TĂTARU-FĂRMUŞ, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania
LAURA BULGARIU, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania, laura.bulgariu@academic.tuiasi.ro

pages 21 - 32   Download
DOI: 10.5281/zenodo.14582031
Abstract
In this study, the effect that inorganic salts have on the solubilization of phosphorus from chemical fertilizers was analyzed. A commercial fertilizer (NKP = 15% - 15% - 15%) and the inorganic salts CuSO4, CaCO3 and CuCl2 were used for the experimental studies. All analyzed samples were obtained by mechanical mixing a constant amount of solid fertilizer with 1 – 2% inorganic salts, followed by their dissolution in distilled water. The obtained results showed that the presence of inorganic salts significantly affects the solubilization of phosphorus, the decrease in the concentration of soluble phosphorus in the obtained solutions being 14.5 – 29.6% lower than in the control sample. An important decrease in the concentration of easily soluble phosphorus can be also observed when fertilizer samples were place in the soil. The presence of inorganic salts leads to a decrease in the concentration of soluble phosphorus in the soil samples by up to 54% compared to the control sample. These results highlight the effect that inorganic salts have on the efficiency of the use of phosphorus chemical fertilizers to increase soil quality.
Keywords: chemical fertilizer, phosphorus solubilization, inorganic salts, soil quality

Circular Economy Solutions: Exploring Agricultural Residues

BOGDAN-MARIAN TOFĂNICĂ, “Gheorghe Asachi” Technical University of Iași, Iași, Romania
ELENA UNGUREANU, “Ion Ionescu de la Brad” Iași University of Life Sciences, Iași, Romania, elena.ungureanu@iuls.ro
OVIDIU C. UNGUREANU, “Vasile Goldis” West University of Arad, Arad, Romania
MARIA E. FORTUNĂ, “Petru Poni” Institute of Macromolecular Chemistry, Iași, Romania
IRINA VOLF, “Gheorghe Asachi” Technical University of Iași, Iași, Romania
VALENTIN I. POPA, “Gheorghe Asachi” Technical University of Iași, Iași, Romania

pages 33 - 48   Download
DOI: 10.5281/zenodo.14582064
Abstract
Agricultural residues, traditionally regarded as waste, represent an abundant and renewable resource that can significantly contribute to a circular economy. By converting crop byproducts like stalks, husks, and straw into valuable bioproducts, industries can reduce reliance on non-renewable resources while minimizing environmental impact. This article explores the potential of agricultural residues, in various applications, including biochemicals, biofuels, bioplastics, packaging materials, biocides, bisorbents and biocomposites. Integrating these residues into production cycles not only reduces waste and conserves natural resources but also provides economic benefits to rural communities and supports sustainable development. Despite challenges like processing costs and logistical issues, advances in technology and supportive policies are accelerating the adoption of agricultural residues in circular economy models to create a closed-loop system where resources are reused, recycled, and repurposed, minimizing waste and conserving natural resources. This shift towards repurposing agricultural waste is essential for building a resilient, low-carbon economy and promoting sustainable resource management.
Keywords: Agricultural residues, Circular economy, Lignocellulosic, Bioproducts, Resource efficiency

Textile Dye Biosorption onto Non-Living Freshwater Green Biomass: Influencing Factors and Its Efficiency. A Case Study (I)

CRINUȚA LARISA ORTOVAN, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania
CARMEN ZAHARIA, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania, carmen.zaharia@academic.tuiasi.ro

pages 49 - 62   Download
DOI: 10.5281/zenodo.14582118
Abstract
This study discusses the experimental results (i.e. discoloration efficiency and Remazol Rosso RB dye removal) performed in application of a biosorption step for treatment of a simulated textile colored wastewater (WW) using dried non-living freshwater green algae-based materials (Spirogyra algae, size < 2 mm) as biosorbent in free form (S1) and after heating at 100°C for 6h (S2). Different influencing factors, i.e. pH, biosorbent dosage, dye concentration, temperature, biosorption time, were studied for finding the best operating conditions for highest discoloration and dye removal degrees. The results indicate that the dried green algal-based material is efficient as biosorbent (i.e. removals of dye and color in range of 64-91% by S1 biosorbent, and 54-85% by S2 biosorbent; mean biosorption capacity of 3.325 - 5.435 mg/g) and may be used in the textile WW treatment for decreasing the organic load and discoloration, especially in the case of frequent WW flowrate and chemical composition variation, when is working in the adequate operating conditions.
Keywords: biosorption efficiency, dried non-living green Spirogyra algae, influencing factors, process variables, Remazol Rosso RB dye, simulated textile wastewater

Cellular Glass-Ceramic from Recycled Residual Glass, Metakaolin and Coal Fly Ash

LUCIAN PĂUNESCU, Daily Sourcing & Research SRL, Bucharest, Romania, lucianpaunescu16@gmail.com
SORIN MIRCEA AXINTE, Daily Sourcing & Research SRL, Bucharest, Romania; National Faculty of Applied Chemistry and Materials Science, University of Science and Technology “Politehnica” Bucharest, Romania
LILIANA MARINESCU, Faculty of Applied Chemistry and Materials Science, National University of Science and Technology “Politehnica” Bucharest, Romania

pages 63 - 76   Download
DOI: 10.5281/zenodo.14582140
Abstract
In this paper, the care for environmental health was promoted, selecting raw materials that meet these requirements. Thus, recycled glass waste in predominant proportion, coal fly ash as a by-product of the energy industry, and a natural alumina-silicate material (metakaolin) were used. Silicon carbide (SiC) was chosen as an expanding agent. Although insignificantly used until now for high-temperature industrial processes, the microwave heating has been adopted to perform the sintering and expanding process. The results showed very good thermal insulation properties and high mechanical strength of the optimal expanded product.
Keywords: glass-ceramic, cellular, glass, metakaolin, coal fly ash

Smart Hydrogels for The Treatment of Oral Cavity Diseases

ADINA MARIA BAROI (DANILA-DEDIU), “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania
MARCEL POPA, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania; Academy of Romanian Scientists, Bucharest, Romania, marpopa2001@yahoo.fr
LEONARD IONUT ATANASE, “Gheorghe Asachi” Technical University of Iaşi, “Cristofor Simionescu” Faculty of Chemical Engineering and Environmental Protection, Iaşi, Romania; Academy of Romanian Scientists, Bucharest, Romania; Faculty of Medicine, Apollonia University of Iași, Romania

pages 77 - 109   Download
DOI: 10.5281/zenodo.14582178
Abstract
The unique environment specific to the oral cavity is suitable for the proliferation of pathogenic bacteria and infections. The effectiveness of drug treatment is often reduced due to the fact that saliva dilutes the mediating formulation and reduces the interaction between the drug and its site of action. An efficient way to solve this problem is the creation of polymeric systems sensitive to the action of stimuli that command the release of the drug at the right place, time and in suitable doses. Due to their ability to respond to stimuli, hydrogels have been applied as an excellent drug-delivery system for treatments that include caries, endodontic diseases, periodontal diseases, bone diseases, mucosal diseases, oral cancer. The present paper proposes a review of recent research in the field of obtaining hydrogels that respond to physical (temperature, UV and visible light) chemical (pH, glucose) and biological stimuli (enzymes) - smart hydrogels -, with applications in the treatment of oral cavity diseases.
Keywords: hydrogels, oral cavity diseases, drug delivery system, stimuli sensitive systems, topical administration

Investigations On the Recycling and Use of Polyethylene Terephthalate - PET (Plastic Bottle) in Asphalt Mixture

CLAUDIU-IONEL CHICUȘ, “Gheorghe Asachi” Technical University of Iași, Faculty of Civil Engineering and Building Services, Iași, Romania, claudiu-ionel.chicus@student.tuiasi.ro
GHEORGHE GUGIUMAN, “Gheorghe Asachi” Technical University of Iași, Faculty of Civil Engineering and Building Services, Iași, Romania
SILVIU CRISTIAN IRICIUC, “Gheorghe Asachi” Technical University of Iași, Faculty of Civil Engineering and Building Services, Iași, Romania
GELU-RĂZVAN GIMIGA, “Gheorghe Asachi” Technical University of Iași, Faculty of Civil Engineering and Building Services, Iași, Romania

pages 111 - 120   Download
DOI: 10.5281/zenodo.14582224
Abstract
The article analyzes the issue of plastic waste, with a particular focus on PET (polyethylene terephthalate), both at the national and global levels, highlighting their environmental impact and the recycling strategies employed to reduce their negative effects. Recipients made of polyethylene terephthalate are among the most widely used plastic materials, especially in the beverage and food packaging industries, and their accumulation in the environment is a major concern due to their high resistance to decomposition. The use of plastic waste, particularly PET (polyethylene terephthalate) bottles, in asphalt mixtures is an innovative solution that is gaining increasing attention both nationally and internationally, in the context of reducing the amount of plastic that ends up in the environment and improving the performance of road infrastructure. PET is one of the most common types of plastic used in packaging, and recycling it presents a significant challenge. In this regard, integrating PET bottles into asphalt mixtures can contribute to reducing plastic waste and improving the durability of road infrastructure.
Keywords: pollution, plastic waste, recycling, roads, sustainable